[3-Chloro-N′-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidato]methanol(methanolato)oxidovanadium(V)
نویسنده
چکیده
In the title complex, [V(C(18)H(11)ClN(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) ion is coordinated by a tridendate 3-chloro-N'-(2-oxidonaphthalen-1-ylmethylidene)benzohydrazidate ligand, one oxido ligand and by O atoms from a methanol and a methoxide ligand, forming a distorted octa-hedral geometry. The dihedral angle between the benzene ring and the naphthyl-ene ring system is 6.4 (3)°. The deviation of the V(V) ion from the plane defined by the three donor atoms of the tridentate ligand and the meth-oxy O atom towards the oxido O atom is 0.323 (2) Å. In the crystal, pairs of inter-molecular O-H⋯N hydrogen bonds form centrosymmetric dimers.
منابع مشابه
{4-Dimethylamino-N′-[1-(2-oxidophenyl)ethylidene]benzohydrazidato}(methanolato)oxidovanadium(V)
The title oxidovanadium(V) complex, [V(C(17)H(17)N(3)O(2))(CH(3)O)O], was obtained by the reaction of 2-acetyl-phenol, 4-dimethyl-amino-benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is five-coordinated by N,O,O'-donor atoms of the Schiff base ligand, one meth-oxy O atom and one oxide O atom, forming a square-pyramidal geometry.
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